Well, yes. And no. Depends.
Newer (all "vapor recovery" and "drive a way protected") setups will give you 91/93/87 whatever you order...
Here's how they work:
The station opens at 5 am. First customer of the day, Joe Blow, rolls in, slides in his CC, pulls the handle out, presses buttons, and the pumps load up. He squeezes the trigger, reducing system pressure, and they kick on, pumping fuel.
When he finishes and replaces the hose handle, a sensor reads an increase in pressure, and the pumps back off. Most of the sytems then wait until the transaction code is processed, and then depressurize the unit & hose clear down to the one way valve (next time, look at the hose. See that metal ring thingy about 2 ~ 3 feet from where the hose comes out of the "box"? That's a combination valve/breakaway, so when your GF drives off w/the hose stuck in the nozzle... well, enough said).
So, you roll up & order up some 93... Ok, there will be a few drops of low grade, but that's it - a few drops, nothing more. Pull up to a newer station today & squeeze the handle - that's exactly how much "previous grade" you'd get. Remember, the operator wants top $$ - any evaporation = lost $$$.
Now in the older systems, one may find more - but still the volumes would be less than a fraction of a liquid cup.
Hope that helps,
J